A 'biogenetic like' synthesis of perloline, 6-(3,4-Dimethoxyphenyl)-5-hydroxy-5,6-dihydrobenzo[c][2,7]naphthyridin-4(3H)-oneExport / Share Share this record       Export this recordPlumX View Altmetrics View AltmetricsDuong, T., Prager, R.H. and Were, S. T. (1983) A 'biogenetic like' synthesis of perloline, 6-(3,4-Dimethoxyphenyl)-5-hydroxy-5,6-dihydrobenzo[c][2,7]naphthyridin-4(3H)-one. Australian Journal of Chemistry, 36 (7). pp. 1431-1440.
Article Link: https://doi.org/10.1071/CH9831431 Publisher URL: https://www.publish.csiro.au/paper/CH9831431 Abstract9H-Indeno[2,1-c]pyridine-1(2H),9-dione, prepared by a new efficient route, reacts with 3,4-dimethoxy- phenyllithium to form the keto alcohol (7), which rearranges with hydrazoic acid to form 5-(3,4- dimethoxyphenyl)benz[c][2,7]naphthyridin-4(3H)-one. The N-oxide photolyses smoothly to yield dehydroperloline as the sole product.
Repository Staff Only: item control page Download Statistics DownloadsDownloads per month over past year |
|
|
| Login | DPI Staff queries on depositing or searching to era.daf.qld.gov.au | |
Export / Share
Export / Share